Primary Anion Exchanger

 
Reduced Throughput
Possible Cause Solution
Increased ionic loading
  · Check influent water analysis
· Increase regenerant
· Add capacity
Channeling, poor distribution
· Suspended solids loading · Check backwash, extend if needed
· Broken or clogged distributors · Repair
· Low flow · Maintain minimum flow
Premature break
  · Check previous run throughput
· If normal regeneration does not restore capacity, double regenerate
· Adjust end point
Regenerant concentration and quantity
  · Check metering pumps, educators, piping, etc.
· Regenerant dosage
· Check dilution flows, time settings
· Apply correct amount at correct concentrations
If degasser (decarbonator) is used
  · Check CO2 at the outlet of the clearwell: should be less than 5 ppm. If not:
· Check air filter on blower; replace if dirty
· Inspect packing (rings) in column. If dirty or slimed, replace packing.
Resin loss
· Excessive backwash · Check temperature and flowrate
· Underdrain failure · Check and repair (resin trap?)
· De-crosslinked resin · See "oxidation"
· Flotation by dissolved gas · Effluent flow control
· Normal bead attrition · Topoff
Resin Age
  · Up to 5%/yr loss in capacity considered normal
· Analyze resin to determine remaining useful life
Resin degradation
· Resin exposed to excessive temperature · Do not exceed 120°F anytime for type I styrenic strong base anion resins
· Do nto exceed 95°F anytime for type II styrenic or type I acrylic strong base anion resins
Excessive rinsing
· Organic fouling (organics tend to hold on to sodium as they contain weak sites which retain sodium) · Partial restoration of resin with a brine squeeze
· Analyze resin for strong base capacity and replace resin if necessary
· Incorporate routine brine squeezes into operation of plant.
· In the case of weak base anions, consider regeneration with ammonia
· Recycle rinse water to reduce water usage
· Adjust rinse end-point
· Check caustic concentration (higher concentration requires more rinse water)
· For high TOC waters, consider the installation of an organic trap
Presence of cation resin in anion bed
  · Analyze resin
· Check for presence of cation resin in anion bed
· Identify cause of presence of cation resin (leaky or broken strainer or lateral) and repair
Resin fouling
· Silica precipitation · Lower caustic strength (2.5% suggested)
· Thoroughfare regeneration (strong base anion/weak base anion) dump first portion of strong base eluate before feeding residual caustic to WBA resin
If degasser (decarbonator) is used
  · Check air filter on blower; replace if dirty, damaged or missing
Note: All of the items listed above for "Reduced Throughput" should also be checked regarding poor effluent quality
Poor Effluent Quality
High conductivity or pH in treated water
· Ran past cation breakpoint · Check cation effluent
· If cation effluent is within acceptable range, check anion resin
Chemical precipitation
· Hardness in regenerant dilution and / or rinse waters · Check for calcium and magnesium in cation and anion effluent
· Insure that dilution and rinse waters are hardness-free
Hardness in treated water
  · Check cation performance
· Check for hardness in all waters used for regeneration to eliminate precipitates
Chloride or silica in treated water
  · Check regenerant specs for chloride and silica content (mercury cell or rayon grades of caustic are acceptable)
· Check for leaking regenerant (caustic) valve
Leaky valve
  · Check bed sample vs. discharge pipe sample (before and after valving); special caution on backwash inlet valve
· Check limit stops on valve operators
· Check air pressure on pneumatic valves
· Check sealing gaskets on multiports
· Check for physical damage due to water hammer
Flow rates too high
· Insufficient reaction time (kinetics) · Reduce flow
Flow rates too low
· Poor distribution, channeling · Place one or more units in Standby to increase flowrate
· Recycle treated water to inlet
Resin fouling
  · See "Resin fouling" above under "Reduced Throughput"
For counter-current regeneration: loss of inert (inactive) resin allows resin migration which, in turn, causes high leakage

In counter-current regeneration, it is important to use soft water for regenerant dilution and displacement rinse
  · Check resin level and add resin as needed
High Pressure Drop
Bed compaction
  · Check flow and temperature for sufficient backwash
· Air or mechanical scour prior to backwash
Resin fines
  · Remove with backwash
Lower water temperature
  · ΔP increases with higher viscosity at lower temperature
Increased flow rate
  · ΔP increases with flow (do not exceed specified ΔP)
Valve partially closed
  · Check and adjust all valves
Internal distributor blockage
· With resin, iron, debris · Inspect strainers and clean
· Repair / clean distributors
Plugged underdrain
· Resin or subfill in collectors outlet strainers · Inspect internals
Resin fouling
  · See "Resin fouling" above under "Reduced Throughput"
Low Pressure Drop
Note: Low pressure drop is not necessarily a problem in itself; however, it may be a symptom of a problem
Reduced flow
  · ΔP decreases with flow
Increased temperature
  · Lower viscosity
· Check backwash rate at higher temperature
Resin loss, reduced bed depth
· Underdrain failure · Check for loss to sewer during backwash abnd rinses
· Resin attrition · Inspect and repair
· Resin loss · See "Resin loss" above under "Reduced Throughput"